abstraction reactions of methyl radicals.
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abstraction reactions of methyl radicals.

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Published in [Toronto] .
Written in English


  • Radicals (Chemistry),
  • Photochemistry,
  • Methyl groups

Book details:

Edition Notes

ContributionsToronto, Ont. University. Theses (M.Sc.)
LC ClassificationsLE3 T525 MSC 1967 D67
The Physical Object
Pagination[67 leaves]
Number of Pages67
ID Numbers
Open LibraryOL17009954M

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  The photolysis of acetone in the presence of various compounds has been investigated between 70°C and °C. If the reaction CH3+CH3=C2H6 has no activation energy, then the activation energies in kcal for the reactions of the type CH3+RH=CH4+R are cyclopropane , cyclobutane , cyclopentane , cyclohexane , benzene , toluene Cited by: Rate data for the abstraction reactions between methyl radicals and some alkanes viz. 2,2-dimethyl­ propane, 2,2,3,3-tetramethylbutane, cyclohexane, butane and 2-methylpropane (containing primary, secondary and tertiary C - H bonds) have Cited by: 1. From the photolysis of acetone in the presence of the nitrogen compounds the following Arrhenius parameters have been determined for hydrogen-abstraction reactions of methyl radicals: [graphic omitted] The results are compared with hydrogen-abstraction reactions involving other nitrogen compounds. You have access to this article. Reactions of methyl radicals with acetaldehyde and acetaldehyde‐d 1. I. relative rates of atom abstraction reactions at °K I. Bárdi. Gas Kinetics Research Group of the Hungarian Academy of Sciences, Szeged, Hungary. Search for more papers by this author. T. by: 7.

Silicon - reaction mechanisms annual survey covering the year Journal of Organometallic Chemistry , 82, DOI: /SX(00)X. R. E. BERKLEY, I. SAFARIK, H. E. GUNNING, O. P. STRAUSZ. ChemInform Abstract: ARRHENIUS PARAMETERS FOR THE REACTIONS OF METHYL RADICALS WITH SILANE AND . FREE RADICALS IN ORGANIC DECOMPOSITION REACTIONS: I. THE THERMAL DECOMPOSITION OF MIXTURES OF METHYL ETHER AND DEUTERO-ACETONE. E. W. R. Steacie and, W. A. Alexander. Published on the web 12 April Author: E. W. R. Steacie, W. A. Alexander. THE REACTIVITY OF PHENYL RADICALS IN ABSTRACTION REACTIONS TOWARD SOME HETEROAROMATIC COMPOUNDS. Iowa State University of Science and Technology Ph.D., Chemistry, organic University Microfilms, Inc., Ann Arbor, Michigan. An assessment of multireference character in transition states is considered to be an important component in establishing the expected reliability of various electronic structure methods. In the present work, the multireference characters of the transition states and the forming and breaking of bonds for a large set of hydrogen abstraction reactions from phenolic compounds by peroxyl radicals Cited by:

By photolysing azomethane in the presence of the silane the following Arrhenius parameters have been obtained for hydrogen-abstraction reactions of methyl radicals: [graphic omitted] The high reactivities of chlorosilanes in free-radical reactions appear to be due to abnormally high A -factors rather than to low activation energies. ABSTRACTION OF HALOGEN ATOMS BY METHYL RADICALS [Szwarc, M] on *FREE* shipping on qualifying offers. ABSTRACTION OF HALOGEN ATOMS BY METHYL RADICALSAuthor: M Szwarc. ω-Phenylalkyl-N-methylcarbarnyl radicals undergo intermolecular addition to 3,3-dinethylbut-l-ene in preference to intramolecular hydrogen abstraction. Methyl N-(ω-phenylalkyl) carbanyl radicals and methyl N-pentylcarbamyi radicals readily abstract hydrogen through a six membered transition state or a seven membered transition state if the Cited by: 9. Arrhenius parameters for the reaction of methyl radicals with (CH3)4M (M = Si, Ge, Sn, Pb) have been measured. A direct correlation of the activation energy .